A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence

Abstract Traditional nonlinear optical (NLO) crystals are exclusively limited to ionic crystals with π ‐conjugated groups and it is a great challenge to achieve a subtle balance between second‐harmonic generation, bandgap, and birefringence for them, especially in the deep‐UV spectrum region ( E g > 6.20 eV). Herein, a non‐ π ‐conjugated molecular crystal, NH 3 BH 3 , which realizes such balance with a large second‐harmonic generation response (2.0 × KH 2 PO 4 at 1064 nm, and 0.45 × β ‐BaB 2 O 4 at 532 nm), deep‐UV transparency ( E g > 6.53 eV), and moderate birefringence (Δ n = 0.056@550 nm) is reported. As a result, NH 3 BH 3 exhibits a large quality factor of 0.32, which is evidently larger than those of non‐ π ‐conjugated sulfate and phosphate ionic crystals. Using an unpolished NH 3 BH 3 crystal, effective second‐harmonic generation outputs are observed at different wavelengths. These attributes indicate that NH 3 BH 3 is a promising candidate for deep‐UV NLO applications. This work opens up a new door for developing high‐performance deep‐UV NLO crystals.