富勒烯
化学
非共价相互作用
计算化学
分子间力
动态共价化学
化学物理
富勒烯化学
背景(考古学)
纳米技术
共轭体系
共价键
分子
超分子化学
有机化学
聚合物
氢键
材料科学
古生物学
生物
标识
DOI:10.1002/cplu.202300062
摘要
The nature and strength of the noncovalent intermolecular interactions on the surface of fullerenes must be understood for the application of these molecules in pharmaceuticals and materials chemistry. Consequently, experimental and theoretical evaluations of such weak interactions have been conducted in parallel. Nevertheless, the nature of these interactions remains a topic of ongoing debate. In this context, this concept article summarizes recent advances in experimental and theoretical efforts aimed at characterizing the nature and strength of non-covalent interactions on fullerene surfaces. Specifically, this article summarizes recent studies conducted on host-guest chemistry based on various macrocycles and on catalyst chemistry based on conjugated molecular catalysts composed of fullerenes and amines. In addition, conformational isomerism analyses performed using fullerene-based molecular torsion balances and state-of-the-art computational chemistry are reviewed. These studies have enabled a comprehensive evaluation of the contributions of electrostatic, dispersion, and polar interactions on the surface of fullerenes.
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