化学
分子内力
氧化磷酸化
组合化学
药物化学
反应中间体
立体化学
有机化学
催化作用
生物化学
作者
Jianing Zhang,Zhenyang Yu,Haofeng Shi,Lingzhi Xu,Yue Song,Yunfei Du
标识
DOI:10.1002/ejoc.202301059
摘要
The reaction of 2‐alkynylanilines with phenyliodonium bis(trifluoroacetate) (PIFA) and diaryl ditellurides was found to conveniently afford the corresponding 3‐aryltelluroindoles via oxidative cyclization/tellurolation. A plausible mechanism involving the in situ formation of the reactive ArTeOCOCF3 from the reaction of PIFA and diaryl ditellurides, and the subsequent oxidative C‐N/C‐Te bond formations was postulated.
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