Optical studies on thermally evaporated Ge–Se/Ge-Sb-Se chalcogenide glass films by spectroscopic ellipsometry

The GexSb30-xSe70: x = 30, 25, 15, 10 glass films were prepared by thermal evaporation technique. The surface morphology of glass films was studied by atomic force microscopy. The samples exhibited surface roughness with a root mean square value falling within the 0.89–1.47 nm range. The optical properties were precisely characterized by spectroscopic ellipsometry in the 4.13–0.77 eV spectral range. The Cody-Lorentz dispersion model was used to fit the data across the entire spectral range and extract the optical functions of glass films. It has been observed that the refractive index, n values rise with increasing energy, reaching a peak, and then experience a subsequent decline. The refractive index values exhibit a rising trend with an increase in Sb content. The optical bandgap, Egopt was found to follow a decreasing pattern with a decrease in Ge content. The refractive index dispersion curve was analyzed using the Wemple and DiDomenico single oscillator model in the lower absorption spectral region. It has been observed the values of oscillator energy, Eo, and static refractive index, n0, exhibit a pattern consistent with that of Egopt , and n, respectively. The optical properties, such as the high-frequency dielectric constant, carrier concentration, plasma frequency, and optical conductivity were analyzed.