生物炭
水热碳化
化学
催化作用
碳化
比表面积
硝基苯
碳纤维
污水污泥
降级(电信)
化学工程
吸附
无机化学
热解
有机化学
污水处理
材料科学
废物管理
工程类
复合数
复合材料
电信
计算机科学
作者
Battuya Byambaa,Eunju Kim,Mingizem Gashaw Seid,Byung-Min An,Jinsoo Cho,Shine Lin Aung,Kyung Guen Song
标识
DOI:10.1016/j.cej.2022.141037
摘要
Nitrogen-doped biochar (HTNBC) was prepared from sewage sludge via hydrothermal route-enabled carbonization, and the optimized HTNBC was found to efficiently activate peroxymonosulfate (PMS) by aiming the less consumption of the chemicals. The optimal HTNBC degraded a 0.1 mM aqueous solution of bisphenol A (BPA) within 10 min at a rate of 0.62 min−1, exhibiting a significantly superior catalytic activity compared to that of pristine sludge biochar. The HTNBC/PMS system effectively oxidized various organic pollutants, including BPA, sulfamethoxazole, 4-chlorophenol, carbamazepine, and nitrobenzene with a low consumption of PMS (1.0 mM) and a low catalyst loading (0.2 g/L). The active sites for PMS activation were identified as graphitic-N, pyridinic-N, and carbonyl groups, besides structural defects and a high specific surface area were also important. The primary oxidation mechanism was anticipated to involve non-radical pathways followed by radical-induced oxidation, in which the surface-bound reactions dominate. The HTNBC/PMS system acts over a wide pH range and exhibits a high resistance to the inorganic anions of natural water. Our results indicate that nitrogen doping via a hydrothermal route allows the fabrication of biochar with a greater abundance of oxygen functional groups, and the specific nitrogen species present within the carbon matrix are also of importance in the development of advanced carbon catalysts.
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