脱氢
乳酸乙酯
催化作用
化学
吸附
动力学同位素效应
X射线光电子能谱
X射线吸收精细结构
水解
无机化学
光化学
有机化学
物理化学
化学工程
光谱学
氘
工程类
物理
量子力学
作者
Shiyao Lu,Jian Zhang,Hao Meng,Xiaoyuan Qin,Jianbin Huang,Yehao Liang,Feng‐Shou Xiao
标识
DOI:10.1016/j.apcatb.2022.122329
摘要
The direct dehydrogenation of ethyl lactate (EL) to produce ethyl pyruvate (EP) over non-precious heterogeneous catalysts is highly desirable, but challenging. Herein, we report a highly efficient silica-supported copper catalyst prepared via a hydrolysis-precipitation method (Cu/SiO2-HP) for the dehydrogenation of ethyl lactate, which exhibited an 85.4 % EL conversion with 91.1 % selectivity toward EP at 320 °C. XAFS, in situ XPS, and CO-adsorption FT-IR spectra revealed that the Cu/SiO2-HP catalyst had abundant Cu0/Cu+ interfaces. In situ FT-IR spectra, kinetic studies, and theoretical calculations also demonstrated that the Cu0/Cu+ interfaces synergistically activate the O−H and C−H bonds in the adsorbed EL for direct dehydrogenation into EP. The H/D kinetic isotope effect for model reaction confirmed that C−H bond activation is the key step in the dehydrogenation reaction. This study offers a new approach toward the selective conversion of EL into EP, which is of great significance for biomass conversion.
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