Recent progress in electrochemical C–N coupling: metal catalyst strategies and applications

. We delineate how the control over nanoscale structures, morphologies, and electronic properties of metal catalysts can optimize their performance in C-N coupling reactions, and discuss the performances and advantages of single-metal catalysts, bimetallic catalysts, and single-atom catalysts under various reaction conditions. By summarizing the latest research achievements, particularly in the development of high-efficiency catalysts, the application of novel catalyst materials, and the in-depth study of reaction mechanisms, this review aims to provide insights for future research in the field of electrochemical C-N coupling, and demonstrates that rationally designed metal catalysts could not only enhance the efficiency and selectivity of electrochemical C-N coupling reactions, but also offer conceptual frameworks for other electrochemical reactions.