催化作用
纳米孔
化学
酶
金属
纳米颗粒
疏水效应
酶催化
有机化学
化学工程
组合化学
材料科学
纳米技术
工程类
作者
Liya Gao,Zihan Wang,Yunting Liu,Pengbo Liu,Shiqi Gao,Jing Gao,Yanjun Jiang
摘要
Chemoenzymatic catalysts with hydrophobic nanopores were fabricated by co-immobilizing metal nanoparticles and enzymes into the dendritic organosilica nanoparticles. They demonstrated highly improved catalytic performance in chemoenzymatic asymmetric synthesis of chiral amines and alcohols. The hydrophobic microenvironment proved to be critical to enhanced stability, activity and cascade efficiency.
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