化学
阳离子聚合
乙二胺
甲醛
配体(生物化学)
甲酸
药物化学
缩合反应
产量(工程)
金属
戒指(化学)
立体化学
高分子化学
无机化学
催化作用
有机化学
生物化学
材料科学
受体
冶金
作者
Sha Sun,Zhi‐Gang Ren,Juhua Yang,Runtian He,Fan Wang,Xianli Wu,Wenping Gong,Hong‐Xi Li,Jianping Liu
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2012-01-01
卷期号:41 (27): 8447-8447
被引量:17
摘要
The reaction of [Ag(MeCN)4]ClO4 with N,N,N′,N′-tetra(diphenylphosphanylmethyl)ethylenediamine (dppeda) in CH2Cl2/MeOH afforded an unexpected cationic binuclear complex [Ag2(L1)2(η,η-μ-ClO4)2](ClO4)2 (L1 = N,N′-bis(diphenylphosphanylmethyl)-3H-4,5-dihydroimidazole-1-ium) (1). Compound 1 was also prepared in high yield from reactions of [Ag(MeCN)4]ClO4 with N,N′-bis(diphenylphosphanylmethyl)ethylenediamine (bdppeda) in the presence of formaldehyde (HCHO) or formic acid (HCOOH). Analogous reactions of AgCl with bdppeda and HCHO resulted in the formation a neutral binuclear complex [Ag2(L2)2(μ-Cl)2] (L2 = N,N-bis(diphenylphosphanylmethyl)-tetrahydroimidazole) (2). Treatment of 1 with concentrated HCl gave rise to a partially anion-exchanged product [Ag2(L1)2(μ-Cl)2](ClO4)2 (3). Compounds 1 and 3 have a similar cationic binuclear structure, in which a [Ag2(η,η-μ-ClO4)2] or [Ag2(μ-Cl)2] ring is sandwiched by two in situ-formed cationic L1 ligands. The L1 ligand may be generated by the Ag(I)-assisted condensation reaction between bdppeda and HCHO or HCOOH. Compound 2 holds a neutral binuclear structure, in which a [Ag2(μ-Cl)2] ring is connected by two in situ-formed L2 ligands from its top and bottom sites. The neutral ligand L2 may be produced from another Ag(I)-assisted condensation reaction between bdppeda and HCHO. The in situ formation of the L1 and L2 ligands provides a new route to the N-heterocyclic diphosphine ligands, and an interesting insight into the coordination chemistry of their metal complexes.
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