氨硼烷
铜
催化作用
氢
无机化学
氨生产
硼烷
制氢
材料科学
氨
化学
壳体(结构)
化学工程
冶金
有机化学
复合材料
工程类
作者
Suresh Babu Kalidindi,Udishnu Sanyal,Balaji R. Jagirdar
摘要
Copper nanoparticles have been prepared by the solvated metal atom dispersion (SMAD) method. Oxidation of the SMAD prepared copper colloids resulted in Cu@Cu(2)O core shell structures (7.7 +/- 1.8 nm) or Cu(2)O nanoparticles depending on the reaction conditions. The nano Cu, Cu@Cu(2)O core shell, and Cu(2)O particles were found to be catalytically active for the generation of hydrogen from ammonia-borane either via hydrolysis or methanolysis reaction.
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