化学
重氮
组合化学
铜
反应条件
有机化学
催化作用
作者
Mingyou Hu,Jian Rong,Wenjun Miao,Chuanfa Ni,Yongxin Han,Jinbo Hu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2014-03-24
卷期号:16 (7): 2030-2033
被引量:123
摘要
A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.
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