材料科学
分子印迹聚合物
石墨氮化碳
循环伏安法
核化学
扫描电子显微镜
检出限
氮化硼
纳米复合材料
氮化碳
甲基橙
化学工程
电化学
纳米技术
化学
色谱法
有机化学
复合材料
选择性
物理化学
催化作用
工程类
光催化
电极
作者
Tuğba Raika Kıran,Necip Atar,Mehmet Lütfi Yola
摘要
Methyl parathion (MP) is an organophosphate chemical agent. Due to low solubility and bioaccumulation, it results in serious health problems. Electrochemical recognition based on graphitic carbon nitride (CN) incorporated hexagonal boron nitride (HBN) nanosheets and molecularly imprinted polymer (MIP) was presented for methyl parathion (MP) detection. Scanning electron microscopy (SEM), X-ray diffraction (XRD) method, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were utilized for characterizations. After that, MP imprinted voltammetric sensor on CN-HBN nanocomposite was carried out in the presence of 100.0 mM pyrrole containing 25.0 mM MP via CV. 1.0 × 10−12–2.0 × 10−9 M and 2.0 × 10−13 M were found as the linearity range and the detection limit (LOD). Finally, MP imprinted sensor was applied to orange juice samples for MP analysis.
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