化学
去相
残留偶极耦合
偶极子
分子间力
核磁共振波谱
分子物理学
分子
结晶学
化学物理
计算化学
核磁共振
物理
立体化学
凝聚态物理
有机化学
作者
Akira Naito,Katsuyuki Nishimura,Satoru Tuzi,Hazime Saitô
标识
DOI:10.1016/0009-2614(94)01073-0
摘要
Both 13C- and 15N-REDOR experiments were performed to determine the 13C-15N interatomic distance in [ 1-13C]N-acetyl-Pro-[15N]Gly-Phe crystal and to evaluate the inter- or intra-molecular dipolar contributions leading to its errors. The interatomic distance was determined to be 3.43 Å after removing the intermolecular contribution to the echo dephasing arising from the intermolecular dipolar interaction with labeled nuclei of the neighboring molecule. This contribution was estimated by extrapolation to infinite dilution of the labeled sample in unlabeled peptide. The theoretical formalism was developed for the nucleus coupled with two heteronuclei. The conformation of this peptide turned out to be β-turn type II on the basis of the abovementioned interatomic distance.
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