超级电容器
材料科学
阳极
阴极
功率密度
碳纤维
电化学
锂(药物)
化学工程
电容器
储能
纳米技术
复合材料
电极
功率(物理)
复合数
化学
电气工程
物理化学
热力学
工程类
内分泌学
物理
电压
医学
作者
Abhik Banerjee,Kush K. Upadhyay,Dhanya Puthusseri,Vanchiappan Aravindan,Madhavi Srinivasan,Satishchandra Ogale
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2014-01-01
卷期号:6 (8): 4387-4387
被引量:159
摘要
Lithium ion hybrid capacitors (Li-HECs) have attracted significant attention for use in next generation advanced energy storage technologies to satisfy the demand of both high power density as well as energy density. Herein we demonstrate the use of very high surface area 3D carbon cuboids synthesized from a metal–organic framework (MOF) as a cathode material with Li4Ti5O12 as the anode for high performance Li-HECs. The energy density of the cell is ∼65 W h kg−1 which is significantly higher than that achievable with commercially available activated carbon (∼36 W h kg−1) and a symmetric supercapacitor based on the same MOF-derived carbon (MOF-DC ∼20 W h kg−1). The MOF-DC/Li4Ti5O12 Li-HEC assembly also shows good cyclic performance with ∼82% of the initial value (∼25 W h kg−1) retained after 10 000 galvanostatic cycles under high rate cyclic conditions. This result clearly indicates that MOF-DC is a very promising candidate for future P-HEVs in a Li-HEC configuration.
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