Intrinsically Microporous Polyesters From Betulin – Toward Renewable Materials for Gas Separation Made From Birch Bark

Abstract Betulin, an abundant triterpene, can be extracted from birch bark and can be used as a renewable monomer in the synthesis of microporous polyesters. Cross‐linked networks and hyperbranched polymers are accessible by an A 2 + B 3 reaction, with betulin being the A 2 monomer and B 3 being a trifunctional acid chloride. Reaction of betulin with a diacid dichloride results in linear, soluble polyesters. The present communication proves that the polyreaction follows the classic schemes of polycondensation reactions. The resulting polymers are analyzed with regard to their micro‐porosity by gas sorption, NMR spectroscopy, and X‐ray scattering methods. The polymers feature intrinsic microporosity, having ultrasmall pores, which makes them candidates for gas separation membranes, e.g., for the separation of CO 2 from N 2 .