A review of pristine and modified biochar immobilizing typical heavy metals in soil: Applications and challenges

In recent years, the application of biochar in the remediation of heavy metals (HMs) contaminated soil has received tremendous attention globally. We reviewed the latest research on the immobilization of soil HMs by biochar almost in the last 5 years (until 2021). The methods, effects and mechanisms of biochar and modified biochar on the immobilization of typical HMs in soil have been systematically summarized. In general, the HMs contaminating the soil can be categorized into two groups, the oxy-anionic HMs (As and Cr) and the cationic HMs (Pb, Cd, etc.). Reduction and precipitation of oxy-anionic HMs by biochar/modified biochar are the dominant mechanism for reducing HMs toxicity. Pristine biochar can effectively immobilize cationic HMs. The commonly applied modification method is to add substances that can precipitate HMs to the biochar. In addition, we assessed the risks of biochar applications. For instance, biochar may cause the leaching of certain HMs; biochar aging; co-transportation of biochar nanoparticles with HMs. Future work should focus on the artificial/intelligent design of biochar to make it suitable for remediation of multiple HMs contaminated soil.