化学
亚胺
共价有机骨架
共价键
堆积
平方(代数)
量子纠缠
堆栈(抽象数据类型)
芴
结晶学
有机化学
聚合物
物理
量子力学
量子
几何学
催化作用
计算机科学
数学
程序设计语言
作者
Fangying Jin,Ha L. Nguyen,Zhiye Zhong,Xing Han,Chenhui Zhu,Xiaokun Pei,Yanhang Ma,Omar M. Yaghi
摘要
Two entangled 2D square covalent organic frameworks (COFs) have been synthesized from 4,4',4″,4‴-(9,9'-spirobi[fluorene]-2,2',7,7'-tetrayl)-tetrabenzaldehhyde (SFTB) and p-phenylenediamine (PPA) and benzidine (BZD) to form COF-38, [(SFTB)(PPA)2]imine, and its isoreticular form COF-39, [(SFTB)(BZD)2]imine. We also report the single-crystal electron diffraction structure of COF-39 and find that it is composed of mutually entangled 2D square nets (sql). These COFs represent the first examples of entangled 2D COF structures, which, as we illustrate, were made possible by our strategy of using the distorted tetrahedral SFTB building unit. SFTB overcomes the propensity of 2D COFs to stack through π-π stacking and allows entanglements to form. This work significantly adds to the design principles of COFs.
科研通智能强力驱动
Strongly Powered by AbleSci AI