卤化物
化学
芳基
间苯二酚
偶联反应
选择性
光化学
离子
催化作用
无机化学
有机化学
烷基
作者
Min Sik Eom,Jieun Noh,Han-Sung Kim,Soyeon Yoo,Min Su Han,Sunwoo Lee
出处
期刊:Organic Letters
[American Chemical Society]
日期:2016-03-28
卷期号:18 (8): 1720-1723
被引量:24
标识
DOI:10.1021/acs.orglett.6b00300
摘要
Mercury complex of 4-(2-pyridylazo)resorcinol (PAR-2Hg(2+)), a halide-ion chemosensor, was prepared and its efficiency as a tool for high-throughput screening (HTS) of transition-metal-catalyzed coupling reactions was investigated. It showed a high selectivity for halide ions. When the PAR-2Hg(2+) complex was used in the Suzuki coupling reaction and C-H activated coupling reaction with aryl bromides, the quantitative and qualitative conversions of aryl halides were obtained from the reaction mixture color change.
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