锰
化学
催化作用
烯烃纤维
同种类的
均相催化
卟啉
组合化学
有机化学
过渡金属
生化工程
纳米技术
材料科学
热力学
物理
工程类
作者
Rose Mary Philip,Sankaran Radhika,C. M. Afsina Abdulla,Gopinathan Anilkumar
标识
DOI:10.1002/adsc.202001073
摘要
Epoxidation of alkenes is a significant reaction in organic chemistry due to its opportunities in producing compounds of biochemical interest. Catalytic epoxidation with first-row transition elements has gained attention in the latest years wherein manganese based catalysts stand superior by satisfying numerous principles of green chemistry. In this review, we have summarized the recent developments in olefin epoxidation using homogeneous manganese catalysts. Manganese complexes with porphyrin, Schiff base, salen, and other non-heme ligands made efficient catalytic systems during the last five years. Notably, we witnessed greener approaches in recent reports wherein photo-catalysis is a promising strategy. We anticipate that the review will benefit the researchers to get a better understanding of the reaction and to choose the best catalysts for their reactions.
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