对映体
手性固定相
多孔性
分子间力
化学
气相色谱法
多孔介质
分子
固定相
分辨率(逻辑)
有机分子
手性拆分
色谱法
有机化学
材料科学
计算机科学
人工智能
作者
Sheng‐Ming Xie,Junhui Zhang,Li‐Ming Yuan
出处
期刊:Methods in molecular biology
日期:2019-01-01
卷期号:: 45-55
被引量:2
标识
DOI:10.1007/978-1-4939-9438-0_3
摘要
The resolution of chiral compounds into optically pure enantiomers is very important in various fields, such as pharmaceutical, chemical, agricultural, and food industries. Chiral gas chromatography (GC) is one of the efficient methods for enantioseparations of volatile compounds. In recent years, porous materials as stationary phases for chromatographic separations have achieved increasing attention. Porous organic cages (POCs) represent an emerging class of porous materials, which are assembled by discrete organic molecules with shape-persistent and permanent cavities through weak intermolecular forces. This chapter describes several chiral POCs as chiral stationary phases for GC enantioseparations of racemic compounds.
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