卤化物
对映体药物
手性(物理)
圆二色性
相(物质)
材料科学
异质结
化学
结晶学
化学物理
无机化学
对映选择合成
光电子学
有机化学
物理
催化作用
手征对称性
量子力学
Nambu–Jona Lasinio模型
夸克
作者
Peng Yu,Yunpeng Yao,Lina Li,Xitao Liu,Mengjie Zhang,Zhenyue Wu,Sasa Wang,Junhua Luo,Weichuan Zhang,Junhua Luo
标识
DOI:10.1002/asia.201900288
摘要
Abstract Organic–inorganic lead halides have recently emerged as promising alternatives to conventional optoelectronic materials, considering their intriguing physical properties. However, organic–inorganic lead halides featuring chirality are seldom explored. Here, a pair of enantiomorphic organic–inorganic hybrid semiconducting lead halides, ( R ‐C 5 H 14 N 2 )PbBr 4 ( 1R ) and ( S ‐C 5 H 14 N 2 )PbBr 4 ( 2S ), were successfully obtained with the templating of chiral amines. These compounds adopt distinct one‐dimensional infinite quantum helices formed by edge‐shared transformative lead bromide octahedra. Notably, 1R and 2S present mirror circular dichroism (CD) signals due to the chirality transfer of the enantiopure amines. Furthermore, 1R and 2S exhibit phase‐matchable quadratic nonlinear response and typical semiconducting behaviours. This work highlights the potential of lead halides as a new kind of chiral semiconducting materials in spintronic and chiral optical applications.
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