激进的
化学
电子顺磁共振
催化作用
降级(电信)
磺胺嘧啶
纳米复合材料
核化学
反应速率常数
动力学
有机化学
纳米技术
核磁共振
材料科学
物理
电信
量子力学
生物化学
抗生素
计算机科学
作者
Yujie Dong,Xinxin Cui,Likun Xu,Xinchi Jian,Qing‐Long Xu,Chaoqun Tan
标识
DOI:10.1016/j.scitotenv.2019.01.280
摘要
Magnetic nanocomposite β-alaninediacetic acid-modified Fe3O4 (β-ADA@Fe3O4) was prepared, characterized and evaluated to activate peroxymonosulfate (PMS) for improved degradation of sulfadiazine (SD). The results reveal that β-ADA@Fe3O4 express more efficient catalytic activity in PMS inducement compared with Fe3O4, and the observed pseudo first rate constant (kobs) of SD degradation is enhanced from 1.05 × 10-2 to 7.02 × 10-2 min-1 when Fe3O4 is replaced by β-ADA@Fe3O4. The highest removal rate 54.0% occurs when [PMS]0 and m(β-ADA@Fe3O4)0 was 0.3 mM and 0.8 g/L at neutral pH. High intensity of hydroxyl radicals (OH) and relatively low intensity of sulfate radicals (SO4-) are distinguished in system by scavenging experiments and electron paramagnetic resonance (EPR) tests. Results point that β-ADA would significantly promote the circulation of Fe2+-Fe3+ on the surface of β-ADA@Fe3O4, producing more radicals (OH, SO4-). The findings herein imply that β-ADA@Fe3O4 is an efficient and green catalyst in activation of peroxymonosulfate under neutral environment.
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