Tuning of Structural Colors Like a Chameleon Enabled by Shape‐Memory Polymers

Nature often uses structuring of materials for coloration rather than incorporating dye molecules, since single-construction materials are capable of producing any vivid visible color in plants and insects. By precisely engineering features that diffract or scatter light, more recently, humans have created similarly intense non-fading colors. Stretchable polymer opals have emerged as a single material which can dynamically shift across the whole visible spectrum using structural colors, by temporary stretching or compression. For energy efficiency and practical considerations, however, it is necessary to fix semi-permanently desired colors without continuous stretching or application of other stimuli or energy. Here, a polymer opal incorporating a shape-memory polymer embedded in its matrix can keep a particular color fixed without the application of external forces, yet can be reprogrammed to a different fixed color on demand. The influence of the material composition on its optical appearance, shape-fixity, and shape recovery abilities in controlled stretch experiments is quantified. High-speed printing-compatible localized compression pattern imprinting is shown to generate stable but easily erasable color patterns. This opens up the potential for durable and energy-efficient yet reusable and reconfigurable displays, wearables, or packaging and security labeling based on such polymeric film materials.