锂钴氧化物
浸出(土壤学)
钴
介孔材料
无机化学
材料科学
锂(药物)
氧化物
氧化钴
化学工程
阴极
晶体结构
粒径
化学
锂离子电池
冶金
催化作用
电池(电)
土壤水分
功率(物理)
结晶学
土壤科学
物理化学
内分泌学
工程类
物理
医学
量子力学
生物化学
环境科学
作者
Mengmeng Wang,Quanyin Tan,Jinhui Li
标识
DOI:10.1021/acs.est.8b03469
摘要
This research presented the impacts of mechanochemical activation (MCA) on the physiochemical properties of lithium cobalt oxide (LiCoO2) powders of cathode materials from spent lithium-ion batteries, and analyzed the relevant effects of these changes on the leaching efficiency of lithium and cobalt and the leaching kinetics of LiCoO2 powders. The results revealed the superiority of MCA in the following levels of changes in the LiCoO2 powders: first, the physical properties included a decrease in the average particle size, an increase in the specific surface area, and the appearance of a mesoporous structure change; second, changes in crystal-phase structures were reflected in the grain refinement of LiCoO2 powders, lattice distortions, lattice dislocations, and storage and increment of internal energy; third, the surface characteristics included a chemical shift of lithium element electrons, a reduction in Co3+ concentration, and an increment in the surface hydroxyl oxygen concentration. These changes in physiochemical properties and structures enhanced the hydrophilicity and interface reactivity of the activated LiCoO2 powders and significantly improved the leaching efficiencies of Li and Co in organic acid solutions. The rate-limiting step of metal leaching was also altered from a surface chemical reaction-controlled one before MCA to an ash layer diffusion-controlled one after MCA.
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