氰化
催化作用
化学
光催化
铱
光催化
光化学
有机催化
蓝光
封面(代数)
可见光谱
磷酸盐
组合化学
有机化学
材料科学
光电子学
对映选择合成
工程类
机械工程
作者
Takayuki Wakaki,K. Sakai,Takafumi Enomoto,Mio Kondo,Shigeyuki Masaoka,Kounosuke Oisaki,Motomu Kanai
标识
DOI:10.1002/chem.201802171
摘要
A catalytic C(sp3)−H cyanation reaction that proceeds under blue-light irradiation was developed. Hybrid catalysis consisting of an iridium photoredox catalyst and a phosphate organocatalyst is key for the success. This picture shows the hybrid catalysis system. There are two gears: the inner gear represents photoredox catalysis, and the outer gear represents the organocatalysis. These gears are driven by blue light (upper right). More information can be found in the Communication by K. Oisaki and M. Kanai et al. on page 8051.
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