材料科学
镀铜
阴极
涂层
阳极
化学工程
集电器
聚合物
分离器(采油)
复合材料
介电谱
电解质
铜
无机化学
电池(电)
锂离子电池
电极
图层(电子)
电化学
冶金
电镀
量子力学
热力学
化学
功率(物理)
物理化学
工程类
物理
作者
Kaiming Xue,Huimin Wang,Pui‐Kit Lee,Shuyu Dong,Denis Y. W. Yu
标识
DOI:10.1021/acsami.1c11181
摘要
A novel 3.3 V copper–lithium battery using a copper foil as the cathode is a potential candidate for next-generation energy storage system due to its simple manufacturing process. However, the cross-over of copper ions from the cathode to the anode limits the reversibility of the battery. Herein, we suppress self-discharge and migration of copper ions in the cell using a commercial polypropylene separator with a coating of polyacrylic acid (PAA), a chelating polymer. Fourier transform infrared spectroscopy confirms that the PAA layer traps the copper ions and prevents them from passing through. The addition of barium titanate nanoparticles into the PAA layer further enhances ionic transfer through the separator and reduces polarization of the cell at high current rates during charge and discharge. The use of a chelating agent with an inorganic filler as a coating layer on the separator is a cost-effective way to improve reversibility and round-trip efficiency of copper–lithium batteries.
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