环氧化物
环加成
催化作用
锌
金属有机骨架
固碳
化学
三唑
组合化学
金属
有机化学
吸附
二氧化碳
作者
Yang Li,Xueqin Tian,Weiwei Jiang,Pengyan Wu,Han-Shu Li,Man Wang,Lin Chen,Jian Wang
摘要
In this study, a novel porous metal-organic framework (MOF) functionalized with amino and triazole moieties has been synthesized. Attributed to the high affinity to CO2 and unsaturated zinc centers, the MOF exhibits high catalytic activity for the CO2 to epoxide cycloaddition reaction, with a turnover number value of up to 10 000 per cycle, and can be reused at least for 20 cycles.
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