材料科学
微观结构
腐蚀
合金
溅射沉积
晶格常数
高熵合金
金属
冶金
薄膜
溅射
化学工程
纳米技术
衍射
光学
物理
工程类
作者
Zhipeng Cai,Zheng Wang,Wenjun Yang,Po Zhang,Yan Lü,Jibin Pu
标识
DOI:10.1016/j.surfin.2021.101558
摘要
In this work, the microstructure and corrosion behavior in 3.5 wt.% NaCl solution, of AlCrTiV-based high-entropy alloy (HEA) films with Cu, Mo, and Cu/Mo, prepared by DC magnetron sputtering, are investigated. The results indicate that all these HEA films are composed of a single BCC phase, but with different lattice constant and different surface topographies. The AlCrTiV, AlCrTiVCu, and AlCrTiVMo HEA films display the surface with tetrahedral nanoparticles, but the AlCrTiVCuMo HEA film shows the surface with near-spherical nanoparticles. Among these HEA films, the AlCrTiVCu HEA film shows the best corrosion-resistance, owing to the dense surface morphology and relatively small surface feature size, but the AlCrTiVCuMo HEA film with the minimum surface feature size has the worst corrosion-resistance, which is due to the obvious holes on its surface and the relatively low content of Al and Cr elements. However, these four HEA films all show a better corrosion-resistance than 304SS, explained by the formation of stable oxides comprising of Al2O3, Cr2O3, etc.
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