SYNTHESIS OF 1-(P-VINYLPHENYL)-2- DIETHYLAMINOMETHYLCYCLOPROPANE AND ITS RADICAL COPOLYMERIZATION WITH METHYL METHACRYLATE
作者
A. I. Sadygova
出处
期刊:Kimya problemləri [Institute of Catalysis and Inorganic Chemistry] 日期:2021-01-01卷期号:19 (3): 173-178被引量:1
标识
DOI:10.32737/2221-8688-2021-3-173-178
摘要
The radical copolymerization of 1-(p-vinylphenyl)-2-diethylaminomethylcyclopropane with methyl methacrylate was carried out and some regularities of the process examined. Values of constants of relative activity of monomers were determined and Q-e parameters calculated on Alfrey and Price. Copolymerization constants of this compound (r1) with methyl methacrylate (r2), calculated on the FinemanRoss method, are as follows: r1 = 0.95, r2 = 0.33, Q and e parameter values: Q1 = 1.80, e1 = -0.72, respectively. The photochemical structuring of the copolymer was studied. It was established that the obtained copolymer has a sufficiently high biomedical activity which opens up the possibility of its using as bactericides and fungicides