双金属片
光催化
材料科学
X射线光电子能谱
纳米颗粒
表面等离子共振
单斜晶系
制氢
等离子体子
复合材料
合金
化学工程
纳米技术
催化作用
光电子学
晶体结构
结晶学
冶金
化学
有机化学
金属
工程类
作者
Jianjun Ding,Xiangyang Li,Lin Chen,Xian Zhang,Xingyou Tian
标识
DOI:10.1016/j.apcatb.2017.10.045
摘要
Plasmonic AuCu bimetallic nanoparticles supported on monoclinic CaIn2S4 have been synthesized through the photoreduction method, by which AuCu bimetallic nanoparticles with different atomic arrangements were site-selectively photo-deposited at the edges of CaIn2S4 surface nanosteps. The obtained plasmonic composites were characterized by XRD, TEM, photoelectrochemical analysis, XPS, UV–vis and PL spectroscopy. The results showed that AuCu bimetallic nanoparticles with alloy structure showed better performance for light absorption, charge separation and photocatalytic activity compared to AuCu core-shell structure. Especially, alloyed Au0.4Cu0.1/CaIn2S4 composite exhibited the highest visible activity for hydrogen production from Na2S/Na2SO3 solution with a rate of 452.8 μmol/h, over 2.2, 10.0, 63.8 and 76.7 times higher than that of core-shell Cu0.1/Au0.4/CaIn2S4, Au0.5/CaIn2S4, Cu0.5/CaIn2S4 and CaIn2S4, respectively. The enhanced photocatalytic performance of AuCu/CaIn2S4 composites could be mainly ascribed to the synergistic effect in AuCu bimetallic nanoparticles and the surface plasmon resonance effect of Au.
科研通智能强力驱动
Strongly Powered by AbleSci AI