Enhanced H 2 O 2 Synthesis by Selective Electrochemical Reduction of Oxygen on Bismuth Phosphate/Oxidized Carbon Nanotube Composites

The electrochemical two‐electron oxygen reduction reaction (2e − ORR) represents a promising on‐site approach for the decentralized and green production of hydrogen peroxide (H 2 O 2 ). Nevertheless, the development of efficient catalysts that exhibit high activity and selectivity remains a significant challenge. Herein, bismuth phosphate/oxidized carbon nanotube composites (BPO/CNTs‐O) constructed via a simple hydrothermal method were used to generate H 2 O 2 in an alkaline environment through electrocatalytic 2e − ORR. With an appropriate BPO content, the BPO/CNT‐O‐3 catalyst demonstrated a high H 2 O 2 selectivity of 91.32% at 0.40 V RHE during the rotating ring‐disk electrode test. Density functional theory calculations indicate that the interaction between monoclinic BPO and CNTs‐O could regulate the interfacial electronic structure and provide a suitable binding strength of oxygen (O 2 ) for subsequent hydrogenation to H 2 O 2 . In a flow‐cell setup, the BPO/CNT‐O‐3‐based cathode could provide a H 2 O 2 yield of 4.0 mol g − 1 cat h −1 with Faraday efficiency around 60%, and the on‐site accumulated H 2 O 2 could rapidly achieve organic dye degradation. This work provides a new perspective on the design and construction of electrocatalytic systems for H 2 O 2 production.