Linkage-Affected Donor–Acceptor Covalent Organic Frameworks for Photocatalytic Hydrogen Production

The depletion of traditional fossil energy and the resulting environmental pollution forces people to explore new energy sources. Direct use of solar energy is now a viable solution for solving these problems. Covalent organic frameworks (COFs) are a porous crystalline material; their well-defined two-dimensional or three-dimensional frameworks can ensure the orderly arrangement of photoelectric active units, giving them potential photoelectric conversion applications. The tunable structural features endow COFs many advantages in photocatalytic hydrogen production under visible light. This review comprehensively summarizes the research progress on photoelectronic donor–acceptor (D-A) COFs with tunable structure for photocatalytic hydrogen evolution and will provide a feasible guiding strategy for applying this type of COFs in photocatalytic hydrogen production.