材料科学
电极
电池(电)
离子
电子
空位缺陷
电荷(物理)
工程物理
量子
光电子学
纳米技术
电子结构
电压
量子化学
密度泛函理论
有机自由基电池
量子点
储能
量子计算机
锂离子电池
化学物理
材料设计
作者
Matthew A. Wright,Ram Seshadri
摘要
Every time a battery is cycled between charged and discharged states, ions and electrons are shuttled between electrodes. In this process, beyond storing charge, the addition and removal of ions in electrodes provides a reversible and tunable handle over the electronic structure and magnetic order. This Research Update paper connects the chemistry of battery electrode materials with the physics of emergent phenomena, including insulator--metal transitions, geometric magnetic frustration, charge and vacancy ordering, and cooperative Jahn--Teller effects. Ion insertion is suggested as being a potentially overlooked handle for the design of functional materials, and open experimental and theoretical challenges are highlighted.
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