鲁米诺
电化学发光
化学
纳米棒
化学发光
光化学
阴极保护
碳酸氢盐
无机化学
过氧化氢
电化学
电极
纳米技术
有机化学
材料科学
物理化学
作者
Zhongyan Xu,Youwen Zhou,Meihua Li,Zhihui Guo,Xusheng Zheng
标识
DOI:10.1021/acs.analchem.3c02066
摘要
The lumiol-O2 electrochemiluminescence (ECL) system constantly emits bright light at positive potential. Notably, compared with the anodic ECL signal of the luminol-O2 system, the great virtues of cathodic ECL are that it is simple and causes minor damage to biological samples. Unfortunately, little emphasis has been paid to cathodic ECL, owing to the low reaction efficacy between luminol and reactive oxygen species. The state-of-the-art work mainly focuses on improving the catalytic activity of the oxygen reduction reaction, which remains a significant challenge. In this work, a synergistic signal amplification pathway is established for luminol cathodic ECL. The synergistic effect is based on the decomposition of H2O2 by catalase-like (CAT-like) CoO nanorods (CoO NRs) and regeneration of H2O2 by a carbonate/bicarbonate buffer. Compared with Fe2O3 nanorod (Fe2O3 NR)- and NiO microsphere-modified glassy carbon electrodes (GCEs), the ECL intensity of the luminol-O2 system is nearly 50 times stronger when the potential ranged from 0 to −0.4 V on the CoO NR-modified GCE in a carbonate buffer solution. The CAT-like CoO NRs decompose the electroreduction product H2O2 into OH· and O2·–, which further oxidize HCO3– and CO32– to HCO3· and CO3·–. These radicals very effectively interact with luminol to form the luminol radical. More importantly, H2O2 can be regenerated when HCO3· dimerizes to produce (CO2)2*, which provides a cyclic amplification of the cathodic ECL signal during the dimerization of HCO3·. This work inspires developing a new avenue to improve cathodic ECL and deeply understand the mechanism of a luminol cathodic ECL reaction.
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