Fe‐Ni2P@NPC Synthesized by Trametes Orientalis as an Efficient Electrocatalyst for the Oxygen Evolution Reaction

Abstract Developing non‐noble metal catalysts for the oxygen evolution reaction (OER) is one of the main challenges in the production of hydrogen energy by water splitting reaction. Herein, taking advantage of the fact that microorganisms have high element contents and metabolic activities, we used them to recycle Ni and Fe from electroplating sludge. Based on the above, we designed a highly efficient oxygen evolution catalyst (Fe‐Ni 2 P@NPC) through the in situ synthesis of Fe‐doped Ni 2 P nanoparticles and N, P dual‐doped carbon materials coupled together. The material exhibited excellent catalytic activity, with a low overpotential of 282 mV at the current density of 10 mA cm −2 along with a fast reaction kinetics, with a small Tafel slope of 57.1 mV dec −1 . This outstanding OER performance is mainly attributed to the in situ doping of Fe in Ni 2 P nanoparticles, resulting in a strong synergistic effect between them. Besides, the strong coupling interaction between Fe‐Ni 2 P and Fe‐NiOOH formed during the OER can adjust the electron distribution and optimize the adsorption capacity of the intermediates. This work provides a reference for the recycling of valuable Ni and Fe metals from electroplating sludge, as well as new insight into the preparation of low‐cost and high‐performance OER catalysts.