Temperature‐Swing Synthesis of Highly Crystalline Covalent Organic Framework Films for Fast and Precise Molecular Separations

, which is 4.5 times higher than the weakly crystalline counterpart. In addition, the molecular sieving test recognize great membrane selectivity to discriminate the antibiotic mixture with a high separation factor of 15.4. This work offers a feasible way for the rational design of the synthesis environment, enabling access to highly crystalline framework materials for targeting molecular separations.