催化作用
材料科学
电极
电池(电)
铂金
透射电子显微镜
极限抗拉强度
化学工程
纳米技术
复合材料
化学
物理化学
热力学
工程类
功率(物理)
物理
生物化学
作者
Haotian Wang,Shicheng Xu,Charlie Tsai,Yuzhang Li,Chong Liu,Jie Zhao,Yayuan Liu,Hongyuan Yuan,Frank Abild‐Pedersen,Fritz B. Prinz,Jens K. Nørskov,Yi Cui
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2016-11-24
卷期号:354 (6315): 1031-1036
被引量:668
标识
DOI:10.1126/science.aaf7680
摘要
Tuning nanoparticle strain The catalytic activity of metals in heterogeneous catalysts can be altered by applying strain, which changes the crystalline lattice spacing and modifies the metal's electronic properties. Wang et al. show how particles of cobalt oxide, a positive electrode for lithium batteries, can expand or contract with charging and transfer strain to adsorbed platinum nanoparticles. For the oxygen reduction reaction used in fuel cells, compressive strain boosted activity by 90%, and tensile strain decreased it by 40%. Science , this issue p. 1031
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