催化作用
化学工程
阴极
溶剂
气体扩散电极
电极
材料科学
气体扩散
制作
扩散
法拉第效率
色散(光学)
纳米技术
化学
电解质
有机化学
工程类
病理
物理化学
医学
物理
光学
替代医学
热力学
作者
Benjamin A. W. Mowbray,Dalimil Dvořák,Nina Taherimakhsousi,Curtis P. Berlinguette
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2021-08-14
卷期号:35 (23): 19178-19184
被引量:20
标识
DOI:10.1021/acs.energyfuels.1c01731
摘要
Cathode gas diffusion electrodes (GDEs) in CO2 electrolyzers facilitate reagent transport and the reduction of CO2 into chemicals and fuels. While GDEs are routinely leveraged to achieve high rates of product formation, design principles for high-performing cathodes have not yet been established. In this report, we demonstrate the influence of a central parameter in GDE fabrication, the catalyst ink solvent, on the properties and performance of spray-coated cathode GDEs. We show that the choice of solvent used during catalyst deposition impacts the faradaic efficiency for CO by as much as 50% at 200 mA cm–2. Moreover, the solvent modulates the surface area, hydrophobicity, and capillarity of GDE catalyst layers. By measuring the hydrodynamic radii of catalyst inks, we conclude that solvent-mediated ionomer aggregation is a key factor that affects the microstructure and properties of GDE catalyst layers. We find that using ethanol as the ink solvent promotes moderate ionomer aggregation and yields the highest performing GDEs. This work describes the influence of electrode fabrication methodologies and demonstrates practical methods for preparing GDEs.
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