塔菲尔方程
过电位
硒化物
计时安培法
纳米复合材料
析氧
化学工程
动力学
化学
材料科学
纳米技术
电极
物理化学
循环伏安法
电化学
有机化学
硒
工程类
物理
量子力学
作者
Xin Zhang,Hongwei Pan,Yubao Jia,Yao Zhang,Zhigang Jiang,Chunjie Li,Li Xu,Lili Bao,Ruguang Ma,Kuikui Wang
标识
DOI:10.1016/j.jcis.2022.04.181
摘要
Sluggish kinetics of the oxygen evolution reaction during the water splitting requires high-performance electrocatalysts with low cost and good stability. Metal-organic frameworks (MOFs) have attracted much attention as electrocatalysts owing to their unique properties. To improve their electrocatalytic activity and stability, we report a selenylation method to modulate the morphology and interfaces by forming flower-like MOF-selenide nanocomposites. The optimal sample exhibits high activity with an overpotential of 260 mV at 10 mA cm-2, much better than commercial RuO2 and the control samples. Moreover, the optimal sample has the lowest Tafel slope of 54.3 mV dec-1, indicating the fast reaction kinetics, which can be attributed to the lower charge-transfer resistance and high intrinsic activity. Chronoamperometry shows that the optimal sample can maintain the current density for 60 h at 10 mA cm-2 after the initial surface reconstruction, demonstrating good stability. This study provides a new perspective on the development of highly efficient electrocatalysts based on polymetallic MOFs.
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