Lead-free double perovskite Cs2NaInCl6 nanocrystals doped with Sb3+ and Tb3+ for copper ions detection in lubricating oil

Detecting heavy metal copper ions in lubricating oil holds immense significance for assessing mechanical wear and predicting mechanical failure. While perovskite nanocrystals offer high sensitivity in detecting copper ions, traditional lead halide perovskites suffer from lead toxicity defects. Lead-free perovskites, like Cs2NaInCl6, avoid the issue of lead toxicity but display lower luminescence intensity due to the presence of forbidden optical transitions. To address these issues, this study synthesized Cs2NaInCl6 nanocrystals (NCs) co-doped with Sb3+ and Tb3+ ions for copper ions detection in lubricating oil. The introduction of Sb3+ effectively reduced the band gap of the Cs2NaInCl6 host, creating an energy transfer pathway for Tb3+ emission via self-trapped excitations (STEs). Moreover, the doping of Tb3+ ions resulted in the suppression of STEs emission due to electron transfer from STEs to Tb3+. The emission of Tb3+ increased initially and then decreased with the increasing Tb3+ concentration, peaking at 40 %. Finally, Cs2NaInCl6: 2.5 %Sb3+, 40 %Tb3+ NCs were employed as probes for copper ions detection, exhibiting superior sensitivity and selectivity compared to similar probes. The presence of copper ions introduced competition between copper and Tb3+ for electrons from STEs, consequently leading to the quenching of multiple emission intensities associated with STEs and Tb3+. This method shows promising potential in predicting mechanical failure.