Promote or inhibit turbulence drag reduction behavior of surfactant solutions with different micelle structures by certain nanoparticle addition

胶束 肺表面活性物质 阻力 化学工程 粘弹性 纳米颗粒 临界胶束浓度 材料科学 化学 热力学 有机化学 纳米技术 水溶液 复合材料 物理 工程类
作者
Xiaoping Li,Hua‐Jie Wang,Yun Zhang,Shengpei Sun,Yu Zhou,Xinlong Lu,Dengwei Jing
出处
期刊:Physics of Fluids [American Institute of Physics]
卷期号:36 (5)
标识
DOI:10.1063/5.0204954
摘要

The micelle structure of surfactant is easy to be destroyed in the flow process resulting in a decrease in its drag reduction (DR) efficiency; therefore, how to strengthen the stability of the micelle structure during the flow process and thus improve the drag reduction efficiency deserves intensive research. In this work, by comparing a variety of nanoparticles, hydrophobic silica nanoparticles were selected as the best additive to enhance the turbulence drag reduction efficiency of surfactant solution with spherical micelle structure. The experimental results also demonstrated that the hydrophobic silica nanoparticles had a reinforcing effect on anionic, cationic, nonionic, and zwitterionic surfactant solutions with the same concentration (dominated by spherical micelles), and the optimal nanoparticle addition concentration and maximum drag reduction rate were obtained. Meanwhile, the effect of silica nanoparticles on the turbulence drag reduction efficiency of surfactant solutions with different micelle structures was evaluated by inducing the surfactant micelle structure change. It was shown that the hydrophobic silica nanoparticles had a strengthening effect on the turbulence drag reduction performance of surfactant solutions with spherical micelle structure, while they had an inhibiting effect on the turbulence drag reduction performance of surfactant solutions with worm-like micelle structure. The change in solution viscoelasticity indicated that the decrease in viscoelasticity was the main reason for the decrease in drag reduction efficiency of surfactant solution with worm-like micelle structure when silica nanoparticles were added. A mechanism for the interaction of hydrophilic/hydrophobic silica nanoparticles with spherical micelles and wormlike micelle structures was finally discussed and proposed.
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