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Homochirality, Stochastic Chiral Reactions, Spontaneous Chiral Ordering of Achiral Molecules, and Similar Chiral Effects. Is there a Physical Basis for these Mirror Symmetry Breaking Phenomena?**

同手性 对映选择合成 手征对称破缺 化学 化学物理 自催化 手性(物理) 对称性破坏 对映体 物理 Nambu–Jona Lasinio模型 有机化学 量子力学 催化作用
作者
В. А. Павлов,Sergey G. Zlotin
出处
期刊:Current Organic Chemistry [Bentham Science]
卷期号:22 (21): 2029-2054 被引量:6
标识
DOI:10.2174/1385272822666180910100449
摘要

This paper presents an overview of known experimental data dealing with the mirror symmetry breaking effect in stochastic reactions (crystallization of NaClO3 from an oversaturated aqueous solution; dissolution-crystallization of the l- and d-NaClO3 crystals mixture under stirring or boiling (Viedma ripening), and similar reactions; Soai reaction of enantioselective autocatalysis and chirality amplification; spontaneous mirror symmetry breaking by molecular self-assembly of achiral molecules and similar reactions in polymerization or liquid crystal media). Stochastic effects of chiral or racemic fields and the effect of chiral memory are discussed as well. P. Curie was convinced that "without asymmetric physical impact no asymmetric chiral effect arises". Recent experimental data that proves the implementation of this criterion is discussed. The aforesaid reactions or effects are considered in terms of a possible chiral impact of external physical inductors as it can be expected for open systems. The meso-form structure of the environment, plasma torch of meteorite impact as a mirror symmetry breaking factor, solar asymmetric irradiation, enantioselective impact of electromagnetic fields (as a combination of the Earth magnetic field and atmospheric electricity), and some other physical inductors are reviewed. The meso-form structure of the gravitational field as a chiral inductor is most consistent with the above– mentioned reactions and effects. Keywords: Homochirality, macromolecular helices, chiral amplification, chiral and racemic fields, solar asymmetric irradiation, enantioselective.
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