吸附
亚甲蓝
聚乙烯醇
朗缪尔吸附模型
物理吸附
吸热过程
化学
朗缪尔
活性炭
超顺磁性
化学工程
弗伦德利希方程
纳米颗粒
活性炭
核化学
材料科学
有机化学
纳米技术
催化作用
物理
磁化
光催化
量子力学
磁场
工程类
标识
DOI:10.3390/magnetochemistry9090211
摘要
As novel methylene blue adsorbents, polyvinyl alcohol and activated charcoal were used to modify the surface of superparamagnetic iron oxide nanoparticles. The adsorption capacity after 69 h was 26.50 ± 0.99–40.21 ± 1.30 mg/g, depending on the temperature (333.15, 310.15, and 298.15 K) and the initial concentration of methylene blue, which was between 0.017 and 0.020 mg/mL. Based on thermodynamics parameters, the adsorption process can be considered to be spontaneous endothermic physisorption. Kinetics studies show that the pseudo-second-order model was the best-fitted model. Adsorption isotherm studies show that the best-fitted models were the Langmuir, Langmuir, and Temkin and Pyzhev isotherm models when adsorbing MB at 333.15, 310.15, and 298.15 K, respectively.
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