材料科学
电介质
铁磁性
纳米棒
潜在井
量子点
复合数
磁化
正交晶系
铁磁材料性能
磁滞
纳米复合材料
带隙
凝聚态物理
纳米技术
复合材料
磁场
结晶学
光电子学
晶体结构
化学
物理
量子力学
作者
Saad Mabrouk Yakout,Ahmed M. Youssef
标识
DOI:10.1016/j.matchemphys.2023.128342
摘要
In this study, new CuS/SnS nanocomposites were simply synthesized by coprecipitation route for capacitive energy storage applications. The results of the XRD analysis confirmed the formation of hexagonal CuS and orthorhombic α-SnS phases. The TEM images of CuS/SnS (1:1) and CuS/SnS (1:3) composites showed the formation of quantum dot particles (2–3 nm) besides nanorods particles (length 56–80 nm and diameter 9–16 nm). The TEM images of CuS/SnS (3:1) sample illustrated the formation of only quantum dot particles (2–3 nm). Infrared band gap energies of 0.8, 0.95 and 1.25 eV were measured for CuS/SnS (1:1), CuS/SnS (3:1) and CuS/SnS (1:3) composites, respectively. CuS/SnS (1:1) composite has a wide hysteresis loop until magnetic field of ±3500 Oe with magnetization (Ms) and coercivity (Hc) values of 0.009 emu/g and 1000 Oe, respectively. For CuS/SnS (1:3) composite, the hysteresis loop possesses a semi-ferromagnetic shape with measured magnetization value of 0.018 emu/g and Hc of 551 Oe. The ferromagnetic order can be attributed to defects as well as the surface interface interaction between CuS and SnS particles. Remarkably, CuS/SnS composites exhibit a giant dielectric constant (>106) with low temperature dependent, making them promising compositions for capacitive energy storage applications. At room temperature, CuS/SnS (1:1), CuS/SnS (3:1) and CuS/SnS (1:3) composites possess colossal dielectric constant values of ∼2.9 × 106, 5.5 × 105 and 6.3 × 106 at frequency of 42 Hz, respectively.
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