超级电容器
材料科学
石墨烯
电解质
电容
兴奋剂
电极
化学工程
纳米线
电荷密度
储能
纳米技术
光电子学
化学
功率(物理)
物理化学
量子力学
物理
工程类
作者
Guifang Li,Xiaohong Fan,Ding‐Rong Deng,Qi‐Hui Wu,Lishan Jia
标识
DOI:10.1016/j.jcis.2023.06.072
摘要
The paper presents a self-assembly approach to synthesize Ni3S2/N, P co-doped graphene (PNG) composite electrode materials for supercapacitors with high energy storage performance and structural stability. Innovatively, the self-assembly approach is induced via the surface charge effect utilizing a two-step hydrothermal method. The doping of nitrogen (N) and phosphorus (P) atoms regulates the surface charge distribution on graphene nanosheets. Therefore, in the synthesized Ni3S2/PNG heterostructures, Ni3S2 nanowires are interwoven into nests and uniformly attached to PNG. The design of the electrode materials with such a special structure not only supports each other to improve the stability of the materials but also facilitates the rapid diffusion of electrolyte ions. Based on the advantages of composition and structure, Ni3S2/PNG has a high specific capacitance of 1117C g-1 at a current density of 1 A/g and excellent rate performance. The asymmetric supercapacitors (ASC) assembled with Ni3S2/PNG and PNG as positive and negative materials respectively have a high energy density of 62 Wh kg-1 at a power density of 158 W kg-1.
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