化学
芳基
戒指(化学)
表面改性
氢化物
立体化学
镍
金属
歧管(流体力学)
计算化学
结晶学
组合化学
药物化学
有机化学
物理化学
机械工程
烷基
工程类
作者
Carlota Odena,Enrique Gómez‐Bengoa,Rubén Martı́n
摘要
Herein, we report the utilization of Ni-Ni species as a manifold for enabling a "ring-walking" event by dynamic translocation of the metal center over the arene backbone. Experimental and computational studies support a translocation occurring via a 1,2-hydride shift. The synthetic applicability of the method is illustrated in a series of C-C bond formations that occur at distal C(sp2)-H sites of simple aryl pivalates.
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