Ion transport and structural design of lithium-ion conductive solid polymer electrolytes: a perspective

Abstract Solid polymer electrolytes (SPEs) possess several merits including no leakage, ease in process, and suppressing lithium dendrites growth. These features are beneficial for improving the cycle life and safety performance of rechargeable lithium metal batteries (LMBs), as compared to conventional non-aqueous liquid electrolytes. Particularly, the superior elasticity of polymeric material enables the employment of SPEs in building ultra-thin and flexible batteries, which could further expand the application scenarios of high-energy rechargeable LMBs. In this perspective, recent progresses on ion transport mechanism of SPEs and structural designs of electrolyte components (e.g. conductive lithium salts, polymer matrices) are scrutinized. In addition, key achievements in the field of single lithium-ion conductive SPEs are also outlined, aiming to provide the status quo in those SPEs with high selectivity in cationic transport. Finally, possible strategies for improving the performance of SPEs and their rechargeable LMBs are also discussed.