Contributed Review: Instruments for measuring Seebeck coefficient of thin film thermoelectric materials: A mini-review

Thin film thermoelectric materials (TF TEMs) based on organic semiconductors or organic/inorganic composites exhibit unique properties such as low-temperature processability, mechanical flexibility, great freedom of material design, etc. Thus they have attracted a growing research interest. Similar to inorganic bulk thermoelectric materials (IB TEMs), the Seebeck coefficient combined with electrical conductivity and thermal conductivity is a fundamental property to influence the performance of TF TEMs. However, due to the differences in material and sample geometries, the well-established characterization devices for IB TEMs are no longer applicable to TF TEMs. And until now, a universal standard of measuring the Seebeck coefficient of TF TEMs is still lacking. This mini-review presents the development of instruments designed for measuring the Seebeck coefficient of TF TEMs in the last decade. Primary measurement methods and typical apparatus designs will be reviewed, followed by an error analysis induced by instrumentation. Hopefully this mini-review will facilitate better designs for a more accurate characterization of the Seebeck coefficient of thin film thermoelectric materials.