金属有机骨架
多孔性
介孔材料
材料科学
纳米技术
配体(生物化学)
化学工程
催化作用
化学稳定性
金属
多孔介质
化学
有机化学
吸附
受体
复合材料
工程类
冶金
生物化学
作者
Guorui Cai,Hai‐Long Jiang
标识
DOI:10.1002/anie.201610914
摘要
The pore size enlargement and structural stability have been recognized as two crucial targets, which are rarely achieved together, in the development of metal-organic frameworks (MOFs). Herein, we have developed a versatile modulator-induced defect-formation strategy, in the presence of monocarboxylic acid as a modulator and an insufficient amount of organic ligand, successfully realizing the controllable synthesis of hierarchically porous MOFs (HP-MOFs) with high stability and tailorable pore characters. Remarkably, the integration of high stability and large mesoporous property enables these HP-MOFs to be important porous platforms for applications involving large molecules, especially in catalysis.
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