化学
吲哚生物碱
吲哚试验
生物碱
对映体
立体化学
巴拉纳斯
红树林
花色曲霉
真菌
曲霉
植物
生物
生态学
幼虫
作者
Runlin Cai,Hao Jiang,Zeen Xiao,Wenhao Cao,Tao Yan,Zhaoming Liu,Shao’e Lin,Yuhua Long,Zhigang She
出处
期刊:Organic Letters
[American Chemical Society]
日期:2019-11-25
卷期号:21 (23): 9633-9636
被引量:40
标识
DOI:10.1021/acs.orglett.9b03796
摘要
A pair of enantiomeric indole diketopiperazine alkaloid dimers [(-)- and (+)-asperginulin A (1a and 1b)] with an unprecedented 6/5/4/5/6 pentacyclic skeleton were isolated from the mangrove endophytic fungus Aspergillus sp. SK-28. The enantiomeric dimers were separated by chiral-phase HPLC. Their structures including absolute configurations were elucidated by spectroscopic analysis, X-ray diffraction, and quantum chemical calculation. (+)-Asperginulin A (1b) exhibited antifouling activity against the barnacle Balanus reticulatus.
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